We added both capacitors before and after the boost converter.
The capacitance also depends on the number of Tx slots of your 2G connection.
In our case only one Tx slot is used or the burst width is limited to 577us.
You need to monitor the current on some equipment and make adjustments.
By the way please note that some Lithium batteries e.g. Li/SOCl₂ cannot support high drain current and it will not work no matter how much capacitance you have added.
In our case we use Lithium Sulphide as well as Lithium Polymer batteries without issues.